COFs covalent organic compound COFs covalent organic compound

产品:MOF&MIL-101(Fe)

Detailed

Product: MIL-101(Fe)
Synonyms: NA
CAS:1189182-67-9

Basic Information
Unit MF. C24O13ClFe3 Unit MW. 699.237
Coordination  Metal Fe Linkers Terephthalic acid (CAS:100-21-0)
Aperture

Aperture:1.2-1.6nm; Pore Size: 2.9-3.4nm

Pore volume 1.8 cm3/g
Surface Area BET Specific surface 2800 m2/g,
Analog Structure
Product Property
Appearance Scarlet Powder
Particle Size 300-600nm
Stability
1) MIL-101(Fe) is stable in air, but decomposed gradually in wet and hot conditions. It is instable and will turn to other forms in polar solvent.
2)Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (such as carbon dioxide) and pollutant air adsorption
2) As Fe-based Lewis acid catalyst
Characterizations
XRD
XRD-MIL-101Fe
BET
BET-mil-101Fe
SEM
SEM-MIL-101(Fe)
FTIR
NA
References
1)D. Lupu, O. Ardelean, G. Blanita, G. Borodi, M. D. Lazar, A. R. Biris, C. Ioan, M. Mihet, I. Misan, G. Popeneciu, Int. J. Hydrogen Energy 2011, 36, 3586, DOI: 10.1016/j.ijhydene.2010.12.043
2)Wang, D.; Huang, R.; Liu, W.; Sun, D.; Li, Z. ACS Catal. 2014, 4, 4254– 4260, DOI: 10.1021/cs501169t

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